The 30-year-old actress looked stunning in a Giambattista Valli feathered creation and let her co-star Kate Beckinsale go black at the London premiere of Total Recall.
Teaming the long sleeved garment with bright Louboutin heels, Jessica admitted that she'd had difficulty walking in the dress.
Monochrome ladies! Kate Beckinsale and Jessica Biel wear opposing black and white dresses at the London premiere of Total Recall
Designer divas: Jessica wore a dress by Giambattista Valli while Kate opted for a Donna Karen number
Kate, on the other hand, could probably move around at ease as her floor-length outfit featured a thigh-high split.
The strapless Donna Karen gown shimmered due to the sequins and Kate teamed it with a pair of black towering Ferragamo heels.
Bright young thing: The New Year's Eve star teamed her feathered dress with a pair of neon heels
Bottoms up! Jessica spent a lot of time posing for photos with waiting fans
Both women spoke about the upcoming remake with Jessica admitting that she did quite a lot to get into shape for the role.
'I did a lot of boxing, kick boxing, martial arts parkour,' she told Mail Online.
Doing an Angelina! Kate was seen laughing as she emphasised the split in her dress
The New Year's Eve star also admitted that while she was in Ireland, she had a taste of their famous tipple.
'We walked into an Irish pub at lunchtime and I got myself a Guinness,' she said. 'It was good it was actually like a soft malt or something.'
The fab four: Kate and Jessica posed up with their co-star Colin Farrell and Kate's husband and director of the film Len Wiseman
Perfect trio: Colin said that the two women were 'lovely' to work with
'I really didn't grow up thinking I would do that. But I suppose I am a bit of a pro now,' she said. 'I love being back in London.'
The main star of the film, Colin, looked very smart in a black suit, a striped tie and shiny shoes.
The Irish star also spoke about being back in his homeland, telling Mail Online: 'It was great being home, surreal having all this there though.
Male co-stars: Colin Farrell and Bill Nighy both wore dark suits to the London event
Generous guy: The Irish star stopped to sign autographs and have his photo taken
Big smiles: Kate looked stunning as she greeted the waiting crowd
Colin added that Kate and Jessica were 'lovely' to work with and said the three of them 'had a good time' making the movie.
'They are both tough girls,' he continued. 'Kate has been fighting vampires for centuries and Jessica grew up in the wilderness.'
A helping hand: Both actresses were seen being assisted as they made their way down the stairs
The Hollywood stars were joined on the red carpet by Bill Nighy who also stars in the film.
Other guests who came along to see it included former glamour model Katie Price and her fiancé Leandro Penna.
The couple arrived wearing all black and Katie made the most of the photo opportunity as she posed next to her beau.
Matching couple: Katie Price and her fiancé Leandro Penna arrived wearing matching black outfits
Leggy ladies: Katie Price and Diana Vickers (R) highlighted their pins in black leggings and skinny jeans
Diana and her boyfriend George Craig posed happily together before heading inside to watch the film
The blonde singer showed off her slender figure in black skinny jeans and a sleeveless and embellished jumper while her beau kept his sunglasses on.
A few female guests tried their best to upstage Kate and Jessica but failed miserably.
Made In Chelsea star Kimberly Garner wore a low-cut cream dress that showed off a lot of skin while actress, Rebecca Ferdinando, showed off even more skin in a cutaway black garment.
Different looks: Kimberley Garner opted for a floor-length dress while Rebecca Ferdinando chose a revealing cutaway dress (R)
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